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杨逍

发布日期:2023-09-07 浏览量:

个人简介

杨逍,理学博士,讲师,硕士生导师。2022年6月毕业于四川大学化学学院,获理学博士学位,现为重庆理工大学化学化工学院基础化学教研室专职教师。在《ACS Catalysis》、《Organic Letters》、《Advanced Synthesis & Catalysis》等国际知名SCI期刊发表一区、二区论文十余篇;主持重庆市教委项目一项,重庆理工大学科研启动项目一项。

研究领域

有机合成,有机方法学,过渡金属催化,可见光氧化还原催化,C-H活化。

承担的主要项目

[1]电氧化过渡金属催化苄胺的C-H氰基化反应研究,重庆市教委科学技术项目,2023-2026,项目负责人

[2]重庆理工大学科研启动项目,2022-2025,项目负责人

代表性成果

1.论文:

[1]Xiao Yang, Rui Sun*. Progress in Transition-Metal-Catalyzed Synthesis of Benzo-Fused Oxygen- and Nitrogen Heterocyclic Compounds from Benzoic Acids.Adv. Synth. Catal.2023,365, 124-141.

[2]Xiao Yang, Rui Sun, Chunchun Zhang, Yan Zhang, Zhishan Su, Yicen Ge, Hua Chen, Haiyan Fu,* and Ruixiang Li*. Chichibabin-Type Phosphonylation of 2-(Hetero)aryl Pyridines: Selective Synthesis of 4-Phosphinoyl Pyridines via an Activated N-benzylpyridinium Salt.Adv. Synth. Catal.2022,364, 2387-239.

[3]Xiao Yang, Rui Sun, Shun Li, Xueli Zheng, Maolin Yuan, Bin Xu, Weidong Jiang, Hua Chen, Haiyan Fu* and Ruixiang Li*, Regioselective Direct C−H Trifluoromethylation of Pyridine,Org. Lett.2020,22, 7108-7112.

[4]Xiao Yang, Rui Sun, Chunchun Zhang, Xueli Zheng,* Maolin Yuan, Haiyan Fu,* Ruixiang Li and Hua Chen, Iridium-Catalyzed Benzylamine C−H Alkenylation Enabled by Pentaflfluorobenzoyl as the Directing Group,Org. Lett.2019,21, 1002-1006.

[5]Rui Sun,Xiao Yang, Yicen Ge, Jintong Song, Xueli Zheng, Maolin Yuan, Ruixiang Li, Hua Chen and Haiyan Fu*, Visible-Light-Induced Oxazoline Formations fromN-Vinyl Amides Catalyzed by an Ion-Pair Charge-Transfer Complex,ACS Catal.2021,11, 11762-11773.

[6]Rui Sun,Xiao Yang, Yicen Ge, Xueli Zheng, Maolin Yuan, Ruixiang Li, Haiyan Fu* and Hua Chen*, Visible Light Induced Synthesis of (Z)-β-iodoenamides from N-Vinyl Amides Mediated by Ion Pair Charge Transfer State,Org. Chem. Front.2022,9, 1975-1981.

[7]Rui Sun,Xiao Yang, Qianggen Li, Ke Xu, Juan Tang, Xueli Zheng, Maolin Yuan, Haiyan Fu*, Ruixiang Li and Hua Chen*, Divergent Synthesis of Isoquinolone and Isocoumarin Derivatives by the Annulation of Benzoic Acid with N-Vinyl Amide,Org. Lett.2019,21, 9425-9429.

[8]Rui Sun,Xiao Yang, Xue Chen, Chunchun Zhang, X. Zhao, Xin Wang, Xueli Zheng, Maolin Yuan, Haiyan Fu,* Ruixiang Li and Hua Chen*, Rh(III)-Catalyzed [4 + 2] Self-Annulation of N Vinylarylamides,Org. Lett.2018,20, 6755-6759.

[9]Shun Li, Wenjing Li,Xiao Yang, Rui Sun, Juan Tang, Xueli Zheng, Maolin Yuan, Ruixiang Li, Hua Chen and Haiyan Fu*, Selective direct C-H polyfluoroarylation of electron-deficient N-heterocyclic compounds,Org. Chem. Front.2020,7, 3887-3895.

[10] Changzhen Yin, Kangbao Zhong, Wenjng Li,Xiao Yang, Rui Sun, Chunchun Zhang, Xueli Zheng, Maolin Yuan, Ruixiang Li, Yu Lan,* Haiyan Fu,* and Hua Chen*, C6-Selective Direct Arylation of 2-Phenylpyridine via an Activated N-methylpyridinium Salt: A Combined Experimental and Theoretical Study,Adv. Synth. Catal.2018,360, 3990-3998.

[11] Wenjing Li, Changzhen Yin,Xiao Yang, Hailong Liu, Xueli Zheng, Maolin Yuan, Ruixiang Li, Haiyan Fu* and Hua Chen*, Cu(II)-Mediated keto C(sp3)–H bond α-acyloxylation of N,N-dialkylamides with aromatic carboxylic acids,Org. Biomol. Chem.2017,15, 7594-7599.

[12] Xiaoxia Duan, Rui Sun, Juan Tang, Shun Li,Xiao Yang, Xueli Zheng, Ruixiang Li, Hua Chen, Haiyan Fu* and Maolin Yuan*, A Facile Synthesis of 2-methylnicotinonitrile through Degenerate Ring Transformation of Pyridinium Salts,J. Org. Chem.2022,87, 7975-7988.

联系方式

电话:13881787551 E-mail:yangxiao@cqut.edu.cn